Chlorine induced stress corrosion cracking testing

Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. In this paper, a chlorideinduced stresscorrosioncracking ciscc test method for spent nuclearfuelstorage canisters is presented. Chloride stress corrosion cracking in austenitic stainless steel. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Crevice corrosion facts and problem solving sandvik. Chloride induced stress corrosion cracking scc is one of the failure modes of stainless steels. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Dunn3, and mekonen bayssieand mekonen bayssie3 1center for nuclear waste regulatory analyses 2southwest research institute san antonio, texas. In order for scc to occur there must be a corrosive environment, a susceptible material, and a driving force.

Chloride induced stress corrosion cracking how is chloride. Abstract stress corrosion cracking scc induced by chlorides frequently causes. Effects of fluoride and other halogen ions on the external. The amount of chlorine contamination for prevention of stress corrosion cracking in sensitized type 304 stainless steel moriyasu tokiwai, hideo kimura and hideo kusanagi central research institute of electric power industry, energy and environmental laboratory, 111. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. To understand the mechanisms behind chlorineinduced stress corrosion cracking ciscc in 304 stainless steel, synchrotron high energy xrays were use. In all cases of failure by stress corrosion cracking, the following three factors must be present. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride. Polymer degradation is a change in the propertiestensile strength, color, shape, etc. The next line of defence in controlling stress corrosion cracking is testing to be sure that materials are safe on a.

Pdf stresscorrosion cracking of aisi 4340 steel in. Chloride induced stress corrosion cracking of stainless. Stress corrosion cracking scc is the cracking induced from the combined influence of. Transformable ferritic steels are susceptible to hydrogeninduced scc in a wide range of aqueous media. Problems with crevice corrosion mainly occur in chloridebearing solutions in combination with a crevice that is wide enough to allow penetration of solutions, but narrow enough to create stagnant conditions. The laboratory testing fails to provide the exact field.

It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Developing field test procedures for chloride stress. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. Stresscorrosion cracking scc is a cracking process that requires the simultaneous action of a corrodent and sustained tensile stress. Chlorideinduced stress corrosion cracking tests and. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. The brass tee fitting fractured due to stress corrosion cracking. The developed tester is easy to use with a standard compacttension. Stress corrosion cracking an overview sciencedirect topics. The impact of scc on a material usually falls between dry cracking and. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014.

The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. This makes these plants susceptible to chlorideinduced stress corrosion cracking cscc. Understanding the risk of chloride induced stress corrosion. Hydrogen formed on the surface of the steel by a cathodic corrosion reaction can diffuse into the. Crevice corrosion is most likely to occur in seawater applications. This makes these plants susceptible to chlorideinduced. The federal materials testing institute, based in duebendorf, switzerland, and the federal materials research and testing institute. The solicitations and topics listed on this site are copies from the various sbir agency solicitations and are not necessarily the latest and most uptodate. Oil and gas production and petrochemical plants in the arabian gulf are exposed to severe environmental conditions of high temperature and humidity. Chlorideinduced stress corrosion cracking tests and example.

It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. Stress corrosion cracking the international institute of. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. Chloride stress corrosion cracking clscc is one the most common reasons why. Stress corrosion cracking facts and how to reduce the risk. The combined observations and analytical results presented below strongly suggest chloride induced stress corrosion cracking as the main failure mechanism, initiating at the exterior surfaces in the vicinity of the welds and under the insulation near the seam between the factoryinstalled and fieldinstalled jackets. The tensile stress may be residual stress resulting from heat treatment. Stresscorrosion cracking of aisi 4340 steel in aqueous. The steel rods had been pitted, causing the roof to cave in. Development of chloride induced stress corrosion cracking. The chloride stresscorrosion cracking behavior of stainless steels. The federal materials testing institute, based in duebendorf, switzerland, and the federal materials research and testing institute of berlin concluded that the collapse was the result of chlorideinduced stress corrosion cracking.

From the chemical composition point of view, corrosion resistant. How uv reduces corrosion in swimming pool structure atg evoqua. The combined observations and analytical results presented below strongly suggest chlorideinduced stress corrosion cracking as the main failure mechanism, initiating at the exterior surfaces in the. Mechanism of chloride stress corrosion cracking of austenitic. Chloride induced stress corrosion cracking how is chloride induced stress corrosion cracking abbreviated. Fractured brass tee fitting metallurgical technologies, inc. Understanding the risk of chloride induced stress corrosion cracking of interim. Stress corrosion cracking requires stresses and a corrosive environment. Chloride induced corrosion of reinforcement steel in concrete. Our water treatment vendor has not made a change in 10 years and we never had a problem.

The relative resistance of a stainless steel to chloride scc is often quantified by the use of standard boiling salt solutions. This chapter begins with a stress corrosion cracking scc definition and characteristics, testing methods common to scc and hydrogeninduced. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 s induced scc. Stress corrosion cracking is the growth of crack formation in a corrosive environment. Developing field test procedures for chloride stress corrosion. In hotsalt stress corrosion cracking of titanium, chlorine is not the cracking agent at the nominal cracking temperature of 29ooc. Initiation and propagation of stress corrosion cracking of. Chloride stress corrosion cracking inspectioneering. Every year there are serious structural failures reported for european for swimming pool buildings, in addition there can also be corrosion of ducts in hvac. Initiation of corrosion of steel in reinforced concrete rc structures subjected to chloride exposures mainly depends on coefficient of chloride diffusion, of concrete. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.

For a given alloy, the testing result depends on the stress state and. Scc test using nacl and mgcl2 as chlorides suggested that mgcl2 was responsible for cracking in the test condition of 353 k with rh35%. Tests for stresscorrosion stresscorrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a. Corrosion engineering our engineers and technicians utilize their academic training, field experience, and advanced analysis tools to identify and help control modes of corrosion and environmental. How to prevent stress corrosion and hydrogeninduced cracking. Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. The residual stresses from the welded brackets, supports and nozzles and the hot humid environment combined with the chloride levels of the insulation provided the necessary conditions for chloride induced stress corrosion cracking to occur. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Based on this series of test results, it was concluded that austeniticstainless steel is susceptible to chloride. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Our low pressure steam boilers water tube design have experienced oxygen pitting after only 5 months of operation. Pdf chloride induced stress corrosion cracking of type. The stainless steel canister inside a dry cask storage system dcss is at risk for chlorine induced stress corrosion cracking scc, especially near welds and at storage sites exposed to high humidity.

A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. Chloride stress corrosion cracking is a well known form of scc, typically. Chlorideinduced stress corrosion cracking tests and example aging management program darrell s. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The hsl research report 902 reference 1 covers the. Chlorideinduced scc is tested experimentally in the laboratory using a chloride containing environment. Electrochemical studies were made in aqueous licl, mgcl 2, and mgbr 2 solutions and in zncl 2 kcl molten salt to clarify the corrosion reactions related to stress corrosion cracking scc of austenitic stainless steel and to better define environmental variables critical to the occurrence of chloride scc. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air article pdf available in zairyotokankyo 523.

Crevice corrosion is regarded as localized corrosion. Chloride stress corrosion cracking is a well known form of scc, typically caused. Development of chloride induced stress corrosion cracking test. Chloride stress corrosion cracking in austenitic stainless steel is. Threshold values and ion distributions at the concretesteel interface. Chloride stress corrosion cracking in austenitic stainless. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking of the highstrength martensitic steel aisi 4340 yield stress1503mpa in nacl aqueous solutions of different concentrations was studied experimentally using compact. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. How uv reduces corrosion in swimming pool structure atg. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Recently we changed out the boilers and feed water system, and now we have a problem.

Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. Pdf chloride induced stress corrosion cracking of type 304. While no stainless steel can be completely immune, swageloks. In situ synchrotron xray tomography of 304 stainless. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 692. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances.

Soilside chlorideinduced stress corrosion cracking under. The amount of chlorine contamination for prevention of stress. A great concern for the longterm integrity of canisters located near the coastline is chloride induced stress corrosion cracking of austenitic stainless steels 3 45. Stress corrosion cracking scc induced by chlorides frequently causes problems in applications where standard austenitic stainless steels are being used.

Pdf chloride induced stress corrosion cracking of type 304 and. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Above 65ooc, however, chlorine does take part in corrosion of titanium. Ctlchloride induced stress corrosion cracking of stainless. Scc usually occurs in certain specific alloyenvironmentstress combinations. Diagnostics of chlorine induced stress corrosion cracking. Where pitting or crevice corrosion causes localised metal loss, the geometry. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Chlorideinduced stress corrosion cracking tests and example aging management program.

The stainless steel canister inside a dry cask storage system dcss is at risk for chlorineinduced stress corrosion cracking scc, especially near welds and at storage sites exposed to high humidity. Testing can be carried out, for example, in boiling 40%. Stress corrosion cracking behavior of nickel base alloys. Diagnostics of chlorine induced stress corrosion cracking using laser ultrasonics sfwst working group meeting may 2224, 2018. Chloride induced stress corrosion cracking listed as ciscc. Mintz1, leonardo caseres2, darrell s dunndarrell s. Tests for stress corrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. The fracture initiated on the id surface of the fitting in the area where the compression ring is crimped to secure tubing to the fitting. The roof was supported by stainless steel rods in tension, which failed. Chlorideinduced stresscorrosion cracking scc is one of the failure.

Although this test may be performed using various concentrations of magnesium chloride, this procedure covers a test solution held at a constant boiling temperature of 155. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Atmospheric salt fog testing to evaluate chloride induced stress. Assessment of susceptibility to chloride stress corrosion. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and. Pitting corrosion of a stainless steel is illustrated in the figure 1. Standard practice for evaluating stresscorrosioncracking.

Chlorine was detected on the fracture surface and id surface of an adjacent nipple. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Jun 08, 20 chloride induced stress corrosion cracking tests and example aging management program darrell s. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Switzerland, and the federal materials research and testing institute of berlin concluded that the collapse was the result of chlorideinduced stress corrosion cracking scc. Chlorideinduced stress corrosion cracking of oxide. Chlorideinduced scc is tested experimentally in the laboratory using a chloridecontaining environment. Initiation strain for chlorideinduced stress corrosion. Equipment that is is hydrotested with chloride contaminated water and left to dry out. The chloride stresscorrosion cracking behavior of stainless. Chloride induced stress corrosion cracking scc of austenitic stainless steel is a potential issue in long term dry storage of spent nuclear fuel canisters.

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